Once the brownie layer is completely cooled, melt the chocolate (6 ounces) in a large microwave-safe bowl, with the microwave set on 50% power, stirring frequently until the chocolate is melted, generally about 1 1/2-2 minutes. Allow the mixture to cool until it's warm, and register 90º-100ºF (32º-38ºC) with an instant-read thermometer.
In a small microwave-safe bowl, heat 3 tablespoons of cream in the microwave until it's 105º-110º F (40º-43ºC), around 15 seconds. Add cocoa (2 tablespoons) and whisk until evenly combined.
Combine the cream and cocoa mixture with sugar (2 tablespoons), a pinch of salt and the remaining cream (1 cup less 3 tablespoons) in the bowl of a stand-up mixture. Using the whisk attachment, set the mixer on medium speed until the mixture begins to thicken, scraping down the bowl as needed. Turn the mixer on high and whisk until soft peaks form, about 2-3 minutes.
Fold 1/3 of the whipped cream mixture into melted chocolate. Gently fold in the remaining whipped cream mixture until evenly combined. Evenly spread mousse to the edges of the cooled pie.
Garnish with cooled topping then refrigerate for 3-4 hours, or better, overnight.